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Author: Bharath GH2

The first hydrogen-powered planes are taking flight

Aircraft retrofitted with hydrogen fuel cells could slash CO2 emissions from small planes — and potentially pave the way for hydrogen jets, new study shows.

A potential solution to carbon-free flying is inching closer to reality.

Since the start of this year, small planes equipped with hydrogen fuel cells have made their first test flights over the U.S. West Coast and the English countryside. The aviation startups ZeroAvia and Universal Hydrogen now claim their novel aircraft will be ready to start flying commercially as early as 2025.

A new analysis suggests that, if the technology can scale, it could sharply reduce greenhouse gas emissions for certain planes — and potentially lay the groundwork for decarbonizing broader swaths of the global aviation market.

Retrofitting a propeller plane with fuel cells and liquid-hydrogen tanks would result in a nearly 90 percent reduction in life-cycle emissions, compared to the original aircraft, according to the International Council on Clean Transportation (ICCT), a nonprofit think tank. That’s assuming the hydrogen is made using only renewable electricity —not with fossil fuels, the way the vast majority of hydrogen is produced today.

Fuel cells work somewhat like batteries. On planes, hydrogen flows into the fuel-cell system and spurs an electrochemical reaction that produces electricity; this in turn drives electric motors and spins propellers. But barring a technological breakthrough, fuel cells can’t produce enough power to carry the large, long-distance aircraft that are responsible for the bulk of aviation’s carbon dioxide emissions.

Instead, the tech will likely be restricted to short-haul, turboprop airliners that can seat roughly 50 to 60 passengers and fly just a few hundred miles, such as the distance from New York City to Washington, D.C. Today’s turboprops represent about 1 percent of global passenger traffic.

Still, experts say fuel cells could help pave the way for larger and more powerful hydrogen models, including potentially jets with combustion engines that burn liquid hydrogen. Airbus and Boeing, the world’s top two aircraft makers, are both developing hydrogen technologies as the industry faces growing public pressure to address climate change.

“The introduction of the fuel-cell aircraft will be the testing ground for just generally using hydrogen in aviation,” Jayant Mukhopadhaya, aerospace engineer and a Berlin-based researcher for ICCT, told Canary Media. ​“How will it work at airports, how is the refueling going to happen, how does hydrogen get delivered, what safety concerns you’re going to have — all of those bits and pieces.”

Why hydrogen is gaining favor

Around the world, commercial air travel accounts for over 2 percent of energy-related CO2 emissions, according to the International Energy Agency. That number is set to soar in the coming years as more oil-burning planes and more passengers hit the skies.

In the near term, airlines and plane manufacturers are working to curb emissions by designing more fuel-efficient engines, electrifying ground operations and increasing their use of ​“sustainable aviation fuel” made from used cooking oil, forestry residues, carbon dioxide and other feedstocks. Last year, alternative fuels accounted for less than 0.1 percent of the total jet fuel used by major U.S. airlines.

Although plant- and waste-based fuels can be cleaner to produce than petroleum-based fuel, they still emit carbon dioxide when burned in engines. Hydrogen does not — that’s why airlines and manufacturers are joining efforts to develop H2-powered aircraft. Fuel cells in particular don’t generate harmful nitrogen oxides or fine particulate matter, since they don’t burn fuel.

A retrofitted fuel-cell aircraft would emit about one-third less CO2 over its lifetime than an aircraft burning ​“e-kerosene,” a type of sustainable aviation fuel made from electricity, water and carbon dioxide, according to the ICCT analysis.

Carbon-intensity of different fueling options, including fossil-based kerosene (“Jet A”); alternative fuel made from electricity, water and CO2 (“e-kerosene”); gaseous hydrogen (“GH2”); and liquid hydrogen (“LH2”). (ICCT)

Hydrogen, especially of the ​green” variety, costs significantly more to make and buy than conventional kerosene. However, because fuel-cell systems are far more energy-efficient than engines, aircraft don’t need to use as much fuel to fly. If green-hydrogen production ramps up and fuel-cell aircraft catch on, it could be cheaper to refuel with H2 than fossil jet fuel in the United States in 2050, the ICCT said in a white paper published on Wednesday.

The most surprising part was the [energy] efficiency impacting the price of fuel,” Mukhopadhaya said. ​That was something we weren’t expecting.”

Hydrogen storage solutions for the net zero energy transition

As the fuel crisis sees an increased interest in low carbon alternative energy carriers, demand for hydrogen looks set to soar. A key barrier to uptake is the development of practical and cost-effective storage solutions.

At the University of Nottingham, a dedicated hydrogen storage group is exploring ways to solve this problem.

The group is led by Professor David Grant and Professor Gavin Walker. David is the Director of the University of Nottingham Energy Institute, while Gavin heads up the University’s Centre for Doctoral Training in Sustainable Hydrogen, where the next generation of hydrogen innovators are being trained.

How it works

The group explores the fundamental and practical aspects of materials that can store hydrogen through a chemical reaction forming a hydride. The advantage of this is that the hydrogen is not in a solid state in the hydride and can be stored at relatively low pressures. A range of new materials are studied, from complex hydrides, high entropy alloys, to cost effective metal hydrides. These can operate at room temperature and elevated temperatures for a range of different applications, from stationary applications through to transport.

Research is wide ranging and complex, and covers areas such as atomistic modelling, machine learning, materials characterisation, and experimental exploration of potential systems. The move to a zero-carbon economy is considered throughout, with sustainability and social acceptance being a key strand of research, alongside potential economic impact.

Many hydrides are attractive as they have energy densities greater than liquid hydrogen in terms of volume. However, the challenge is to reduce mass and cost of the hydride materials and avoid excessive weight from the tank and supporting infrastructure itself so that the total system is competitive. This is particularly challenging for transport applications, therefore, many of the projects also develop practical demonstrators. These address scale up and system issues such as thermal management and the design of internal and external architectures of the storage tanks to maximise the potential.

The group is one of the largest in the UK, with hydrogen demonstrators, and impressive, purpose built hydrogen laboratories, situated in the Research Acceleration and Demonstration building on the Jubilee Campus at the University of Nottingham.

Current projects

Dual-use energy storage

This Engineering and Physical Sciences Research Council (EPSRC) funded project aims to produce a highly efficient, innovative, and cost-effective dual-use hydrogen storage technology that can be used in a range of industrial cooling processes, including delivering hydrogen to a fuel cell and generating direct cooling for refrigeration.

Ocean Refuel

The EPSRC funded Ocean-REFuel programme brings together a multidisciplinary team to establish fundamental scientific and engineering understanding for the conversion of ocean renewable energy such as offshore wind, to liquid and gaseous fuels. Led by the University of Strathclyde, the initiative draws on the expertise of the Universities of Nottingham, Cardiff, Imperial, and Newcastle.

MariNH3

This multi-disciplinary EPSRC programme seeks to decarbonise marine transport through innovation in ammonia thermal propulsion. As part of this, the storage of fuel mixed with hydrogen will be explored. Led by the University of Nottingham, key partners include the Universities of Cardiff, Birmingham, Brighton and the Science and Technology Facilities Council (STFC).

High-Store

This Business, Energy, and Industrial Strategy (BEIS) funded project is exploring high temperature hydrogen stores that can use a cheap metal hydride with an energy density superior to that of compressed gas and liquid hydrogen. The initiative is a collaboration with independent research and technology organisation TWI, and Chesterfield Special Cylinders.

Demonstrator projects

These are many and varied. One example is the CitiBus project, where hydrogen stores feed fuel cells and electric machines. This work is undertaken in partnership with the Power Electronics and Machine Centre at the University of Nottingham and is funded by Local Enterprise Partnership (D2N2), the Energy Research Accelerator, and the Propulsion Futures Beacon.

Other key projects explore stores for marine and off-road vehicles that use hydrogen combustion engines. Research is in partnership with the University’s Low Carbon Internal Combustion Group.

Hydrogen research map

Scientists produce green hydrogen from seawater

SCIENTISTS have developed a system that can produce green hydrogen directly from seawater without the need for any pre-treatment processes like desalination. The team behind the development, which involves the introduction of a Lewis acid layer on a transition metal oxide catalyst, say the method shows high potential for commercial application.

Over 97% of the water on Earth’s surface is saline water in the oceans, 2% is stored as fresh water in ice caps, glaciers and snow-capped mountain ranges, and just 1% is available for our daily water supply needs.

Saline water can be made into potable water through a process called desalination, a technique that some areas around the world rely on to produce fresh water for human consumption and for domestic and industrial use. But desalination is an energy-demanding process, and worse still it is often powered by energy sources which are unsustainable.

Splitting water into its constituent parts is also well understood. The process – known as electrolysis – uses a direct current between two electrodes immersed in an electrolyte to split water into hydrogen and oxygen. Hydrogen is formed at the cathode, or negative electrode, and oxygen at the positive electrode, or anode.

Because a mix of the gases can explode, most electrolysers separate the anode and cathode with a thick, porous plastic sheet, and metal catalysts such as nickel and iron are used to speed up reactions.

Putting both of these processes together, namely desalinating seawater, and then splitting it to create hydrogen has long been hailed as one of the best solutions to provide clean and affordable fuel for energy, that in turn could power everything from a city’s electricity, to making steel, producing fertiliser, and even as fuel for airplanes – the list of potential uses is a long one.

However, one of the reasons we’re not already using hydrogen fuel to fly around the world, is that saltwater and other impurities corrode electrodes, shortening their life. As those components are typically made of rare metals such as platinum, it costs too much to keep replacing them. Chloride ions in seawater are also a problem and chlorine electro-oxidation reactions (ClOR) compete with oxygen evolution reaction (OER) on the anode during electrolysis. This reaction results in the release of toxic and corrosive chlorine species such as hypochlorite. Hypochlorite is relatively unstable, it can release toxic chlorine gas when mixed with ammonia or acid and it can also eat away at stainless steel.

To get around this, the seawater could be desalinated and purified before processing it, but this is not always financially viable either. Another option is to coat the electrodes with polyanions to suppress corrosion, but this too can be costly.

Lewis acid layer on a metal oxide catalyst

Scientists working on the problem have now found another solution using cheaper materials. Instead of using catalysts made of rare precious metals to dynamically split water molecules and capture hydroxyl anions, the team introduced a Lewis acid layer (chromium oxide), on a transition metal oxide catalyst, which promotes water splitting to H and OH. “This is a general strategy that can be applied to different catalysts without the need for specifically engineered catalysts and electrolyser design,” write the authors in their research paper.

Captured hydroxyl anions can then be oxidised into oxygen molecules with anodic potential, and as the process produces large amounts of OH−, it reduces the amount of Cl− that is formed. “These results demonstrate that the harmful Cl− chemistry in direct seawater electrolysis can indeed be avoided by preferentially enriching OH− on the electrode surface,” the authors write.

Additionally, the team only filtered the seawater to remove solids and microorganisms, but did not purify it beforehand, which is a step that is normally needed when using conventional electrolysers.

“The performance of a commercial electrolyser with our catalysts running in seawater is close to the performance of platinum/iridium catalysts running in a feedstock of highly purified deionised water,” explains co-author Yao Zheng at the University of Adelaide, adding that the experiment is nearly 100% efficient when producing green hydrogen from splitting seawater. As such is could help negate the need to use freshwater – a commodity that is already scarce.

The team hopes to scale up their project for commercial production in ammonia synthesis, and to generate hydrogen fuel cells.

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